Institute of Applied Physics : Laboratory of Physical Methods of Solid State Investigation "Tadeusz Malinowski"

Laboratory of Physical Methods of Solid State Investigation was founded in 1957 and is named after a famous physicist Tadeusz Malinowski.

The laboratory possesses a range of performant/unique equipment and facilities, some of which are also available to non-IFA researchers. E.g:

2025

Lozovan, V.; Kravtov, V.Ch.; Bulhac, I.; Petuhov, O.; Vlase, T.; Bourosh, P.N. Tetraaza macrocyclic complexes of Cu(II), Co(III) and Ni(II) derived from template condensation of 2,6-pyridinedicarbohydrazide and 2,6-diacetylpyridine: Stability investigation and coloring properties on plastics. J Mol Struct. 2025, 1321(3), 140021. Doi: 10.1016/j.molstruc.2024.140021 (IF: 4,0).

2024

Chumakov, Y.; Graur, V.; Graur, I.; Tsapkov, V.; Garbuz, O.; Gulea, A. Insights into Antiradical Behavior: Crystal Structures and DFT Analysis of 2-Formylpyridine N⁴-Allylthiosemicarbazone Salts. Acta Chim Slov. 2024, 71, 609—618. Doi: 10.17344/acsi.2024.8728 (IF: 1,2).
Malpicci, D.; Forni, A.; Lucenti, E.; Marinotto, D.; Maver, D.; Lozovan, V.; Kravtsov, V.C.; Siminel, A.; Fonari, M.S.; Cariati, E.M. Excitation Dependent Multiemissive Behaviour of Triimidazole Carboxylic Acid anti‐Kasha Luminophore and its Mononuclear Metal Complexes. Eur J Inorg Chem. 2024, 27(13), e202400338. Doi: 10.1002/ejic.202400338 (IF: 2,2).
Ureche, D.; Bulhac, I.; Bourosh, P. New (o-phenylenediaminglyoximato)-(o-phenylenediaminglyoxime)zinc(II) chloride. Synthesis and crystal structure. Acta et Commentationes, Exact and Natural Sciences. 2024, 17(1), 32—41. Doi:10.36120/2587-3644.v17i1.32-41.
Cocu, M.A.; Bourosh, P.N.; Kravtsov, V.Ch.; Danilescu, O.S.; Bulghac, I.I. Mononuclear Nickel(II) and Copper(II) Coordination Compounds with Ligands Based on Acetyl(benzoyl)acetone S-Methylisothiosemicarbazones and 8-Quinolinecarboxaldehyde. Synthesis and Crystal Structure. Russ J Coord Chem. 2024, 50(3), 217—225. Doi: 10.1134/S1070328423601267 (IF: 1,1).
Коку, М.А.; Боурош, П.Р; Кравцов, В.Х.; Данилеску, О.С.; Булхак, И.И. Моноядерные координационные соединения никеля(II) и меди(II) с лигандами на основе S-метилизотиосемикарбазонов ацетил(бензоил)ацетона и 8-хинолинальдегида. Cинтез и кристаллическая структура. Координационная химия. 2024, 50(3), 209—219. Doi: 10.31857/S0132344X24030061.
Nijhuis, M.R.; Yamba, Z.; Novikov, E.; Fonari, M.S.; Timofeeva, T.V.; Castañeda, R. A Series of Zinc Mononuclear Complexes with Imidoyl Amidine Ligands: Syntheses, Crystal Structures, and Photoluminescence Properties. Chemistry. 2024, 6(4), 760—772. Doi: 10.3390/chemistry6040045.
Graur, I.; Graur, V.; Cadin, M.; Garbuz, O.; Bourosh, P.; Melnic, E.; Lozan-Tirsu, C.; Balan, G.; Tsapkov, V.; Fala, V.; Gulea, A. Synthesis and Characterization of Copper(II) and Nickel(II) Complexes with 3-(Morpholin-4-yl)propane-2,3-dione 4-Allylthiosemicarbazone Exploring the Antibacterial, Antifungal and Antiradical Properties. Molecules. 2024, 29(16), 3903-1—3903-18. Doi: 10.3390/molecules29163903 (IF: 4,6).
Culeac, I.; Verlan, V.; Bordian, O.; Melnic, E.; Podgornii, D.; Bulhac, I.; Cojocaru, I.; Moise, C.; Ghenea, V.; Siminel, A.; Enachescu, M. Structure and photoluminescence properties of coordination compound [Eu₂(o-MBA)₆(phen)₂] with high quantum yield. J Lumin. 2024, 276, 120854-1—120854-9. Doi: 10.1016/j.jlumin.2024.120854 (IF: 3,6).
Stati, D.; van Leusen, J.; Kravtsov, V.Ch.; Krämer, K.W.; Liu, Sh.-X.; Decurtins, S.; Kögerler, P.; Baca, S.G. Hexadecanuclear isobutyrate nanoclusters with a {Co^II₁₄Co^III₂} core. CrystEngComm. 2024, 26(32), 4264—4271. Doi: 10.1039/D4CE00637B (IF: 3,1).
Novikov, E.M.; Campos, J.G.; Read de Alaniz, J.; Fonari, M.S.; Timofeeva, T.V. Synthesis, molecular and crystal structures of 4-amino-3,5-difluorobenzonitrile, ethyl 4-amino-3,5-difluorobenzoate, and diethyl 4,4′-(diazene-1,2-diyl)bis(3,5-difluorobenzoate). Acta Crystallogr E. 2024, 80(8), 867—872. Doi: 10.1107/S2056989024006819 (IF: 0,9).
Terenti, N.; Lazarescu, A.; Shova, S.; Bourosh, P.; Nedelko, N.; Ślawska-Waniewska, A.; Zariciuc, E.; Lozan, V. Synthesis, X-ray and antibacterial activity of new copper(II) thiosemicarbazone complexes derived from 4-formyl-3-hydroxy-2-naphthoic acid. Inorg Chim Acta. 2024, 571, 122216-1—122216-10. Doi: 10.1016/j.ica.2024.122216 (IF: 2,8).
Болотин, О.А.; Гончарук, В.П.; Болога, М.К.; Митина, Т.Ф.; Поликарпов, А.А.; Кострюкова, Н.В. Активация цеолита в магнитоожиженном слое. Электронная обработка материалов. 2024, 60(3), 50—55. Doi:10.52577/eom.2024.60.3.50.
Novikov, E.M.; Castañeda, R.; Fonari, M.S.; Timofeeva, T.V. A 1:1 flavone cocrystal with cyclic trimeric perfluoro-o-phenylenemercury. Acta Crystallogr E. 2024, 80(7), 717—720. Doi: 10.1107/S2056989024005346 (IF: 0,9).
Kravtsov, V.; Bold, V.; Siminel, N.; Chumakov, Y.; Gdaniec, M.; Lucenti, E.; Malpicci, D.; Maver, D.; Fonari, M. Stimuli-Responsive Photoluminescence of Eu(III) Complexes with Triazine-Based Luminophores. Cryst Growth Des. 2024, 24(12), 4875—4883. Doi: 10.1021/acs.cgd.4c00205 (IF: 3,8).
Danilescu, O.; Bourosh, P.; Bulhac, I.; Shova, S.; Kravtsov, V.Ch.; Caraba, M.N.; Caraba, I.V.; Popescu, R.; Crisan, M.; Haidu, D.; Kulikova, O.; Costriucova, N.V.; Petuhov, O.; Croitor, L. Laminated dihydrazone Zn(II) coordination polymer with prospects for sensory and multifunctional biomedical applications. Polyhedron. 2024, 258, 117039-1—117039-11. Doi: 10.1016/j.poly.2024.117039 (IF: 2,6).
Cocu, M.A.; Bourosh, P.N.; Kravtsov, V.Ch.; Danilescu, O.S.; Bulhac, I.I. Mononuclear Nickel(II) and Copper(II) Coordination Compounds with Ligands Based on Acetyl(benzoyl)acetone S-Methylisothiosemicarbazones and 8-Quinolinecarboxaldehyde. Synthesis and Crystal Structure. Russ J Coord Chem. 2024, 50(3), 217—225. Doi: 10.1134/S1070328423601267 (IF: 1,9).
Ursaki, V.; Braniste, T.; Zalamai, V.; Rusu, E.; Ciobanu, V.; Morari, V.; Podgornii, D.; Ricci, P.C.; Adelung, R.; Tiginyanu, I. Aero-ZnS prepared by physical vapor transport on three-dimensional networks of sacrificial ZnO microtetrapods. Beilstein J Nanotech. 2024, 15, 490—499. Doi: 10.3762/bjnano.15.44 (IF: 3,1).
Gogia, A.; Novikov, E.M.; Guzei, I.A.; Fonari, M.S.; Timofeeva, T.V. Crystal structure and characterization of a new one-dimensional copper(II) coordination polymer containing a 4-aminobenzoic acid ligand. Acta Crystallogr E. 2024, 80(3), 330—334. Doi: 10.1107/S2056989024001336 (IF: 0,9).
Crisan, M.; Muntean, C.; Chumakov, Y.; Plesu, N. Investigating the Corrosion Inhibition Mechanisms of Alkanolammonium Salts: A Case Study with Ethylethanolammonium 4-Nitrobenzoate on Carbon Steel in Saline Solution. Appl Sci - Basel. 2024, 14(5), 1832-1—1832-17. Doi: 10.3390/app14051832 (IF: 2,7).

Craciun, N.; Melnic, E.; Kulikova, O.V.; Siminel, A.V.; Chisca, D.; Fonari, M.S. Interplay of bipyridine and 4,4′-diaminodiphenylmethane ligands in crystal design of cadmium-based coordination polymers: Structures and unusual photoluminescence quenching. Polyhedron. 2024, 251, 116850-1—116850-10. Doi 10.1016/j.poly.2024.116850 (IF: 2,6).
Terenti, N.; Nedelko, N.; Melnic, E.; Preda, S.; Fruth, V.; Latuch, J.; Kravtsov, V.Ch.; Slawska-Waniewska, A.; Lazarescu, A.; Lozan, V. Heterometallic Co–Sr -2,3-pyridinedicarboxylate complex and its related perovskite oxide: Synthesis, structural characterization and magnetic properties. J Solid State Chem. 2024, 331, 124538-1—124538-7. Doi: 10.1016/j.jssc.2023.124538 (IF: 3,3).

Brevete de invenție (Patents)

Danilescu, O.; Bulhac, I.; Cocu, M.; Bouroş, P.; Ciloci, A.; Clapco, S.; Labliuc, S.; Dvornina, E. Perchlorat de 2,6-diacetilpiridin-bis(picolinoilhidrazon)-bis( aqua)fier(III))-hidrat(1/2,5) cu proprietăți de stimulator al sintezei lipazelor la tulpina de fungi Rhizopus arrhizus CNMN FD 03. Brevet de Invenție nr. MD 4874 B1 2023.11.30.

2023

Talmaci, N.; Dragancea, D.; Gorincioi, E.; Bourosh, P.; Kravtsov, V. Crystal structure and NMR spectroscopic characterization of 1,5-bis(2-hydroxy-3-methoxybenzylidene)carbonohydrazide. Chemistry Journal of Moldova. 2023, 18(2), 53—60. Doi: 10.19261/cjm.2023.1074.
Graur, I.; Bespalova, T.; Graur, V.; Tsapkov, V.; Garbuz, O.; Melnic, E.; Bourosh, P.; Gulea, A. A new thiosemicarbazone and its 3d metal complexes: Synthetic, structural, and antioxidant studies. J Chem Res. 2023, 47(6), 1—8. Doi: 10.1177/17475198231216422 (IF: 1,4).
Podgornii, D.; Shova, S.; Kravtsov, V.Ch.; Baca, S. A. Nanosized Heteronuclear {Fe₁₈Tb₆} Coordination Wheel Based on Pivalate and Triethanolamine Ligands. În: IFMBE Proceedings, vol 91. Springer, Cham. Volume 1: Nanotechnologies and Nano-biomaterials for Applications in Medicine. 6th International Conference on Nanotechnologies and Biomedical Engineering, September 20–23, 2023, Chisinau, Moldova , p. 80—87. Doi: 10.1007/978-3-031-42775-6_9.
Cengiz, A.; Goren, S.; Sonmez, A.; Șale, Y.; Okumuș, E.; Kirbaș, C.; Chumakov, Y.M.; Seydov, M.-H.Y. Modification of the optical and elastic properties of TlGaSe₂ layered semiconductor produced by the memory effect. Phys Scripta. 2023, 98(12), 125006. Doi:10.1088/1402-4896/ad0082 (IF: 2,9).
Rusnac, R.; Garbuz, O.; Chumakov, Y.; Tsapkov, V.; Hureau, Ch.; Istrati, D.; Gulea, A. Synthesis, Characterization, and Biological Properties of the Copper(II) Complexes with Novel Ligand: N-[4-({2-[1-(pyridin-2-yl)ethylidene]hydrazinecarbothioyl}amino)phenyl]acetamide. Inorganics. 2023, 11(10), 408-1—408-17. Doi: 10.3390/inorganics11100408 (IF: 2,9).
Begeç, S.; Yuksel, F.; Chumakov, Y.; Alataş, S.; Kılıç, A. Phenolysis of 2, 2′-Biphenoxy Thiophosphinic Chloride: Crystal Structures and DFT Calculations of 2, 2′-Biphenyl 4-Tert-Butylphenyl Thiophosphinate and 2, 2′-Biphenyl 3,4-di-Methylphenyl Thiophosphinate. Polycycl Aromat Comp. 2023, 34(8), 7426—7438. Doi: 10.1080/10406638.2022.2136721 (IF: 2,4).
Darii, M.; van Leusen, J.; Kravtsov, V.Ch.; Chumakov, Y.; Krämer, K.; Decurtins, S.; Liu, Sh.-X.; Kögerler, P.; Baca, S.G. {Mn₆^IIIMn^IVDy₂^III} Single-Molecule Magnet Based on Cubane Subunits. Cryst Growth Des. 2023, 23(9), 6944—6952. Doi: 10.1021/acs.cgd.3c00783 (IF: 3,8).
Averkiev, B.B.; Castañeda, R.; Fonari, M.S.; Jucov, E.V.; Timofeeva, T.V. Additive controlled packing polymorphism in a series of halogen-substituted dithieno[3,2-a:2′,3′-c]phenazine derivatives. CrystEngComm. 2023, 25(28), 4076—4088. Doi:10.1039/D3CE00387F (IF: 3,756).
Craciun, N.; Chisca, D.; Melnic, E.; Fonari, M.S. Unprecedented coordination compounds with 4,4′-diaminodiphenylethane as a supramolecular agent and ditopic ligand: Synthesis, crystal structures and Hirshfeld surface analysis. In: Synthesis, Crystal Structures and Hirshfeld Surface Analysis of Coordination Compounds (Volume II), pp. 129-142. Ed.: Waldemar Maniukiewicz, MDPI: Basel, 2023, ISBN 978-3-0365-7929-0.
Литвинчук, І.В.; Фонарь, М.С.; Кравцов, В.Х.; Гельмбольдт, В.О. Експериментальне дослідження перетворення 2-амінофенілоцтової кислоти гексафторосилікату на 2-оксіндол у м’яких умовах. Фармацевтичний журнал. 2023, 78(2), 15—19. Doi: 10.32352/0367-3057.2.23.02.
Terenti, N.; Melnic, E.; Fruth, V.; Nedelko, N.; Aleshkevych, P.; Lewinska, S.; Slawska-Waniewska, A.; Kravtsov, V.Ch.; Lazarescu, A.; Lozan, V. Synthesis and microstructure of BaMnO₃ oxide obtained from coordination precursor. J Solid State Chem. 2023, 324, 124108-1—124108-7. Doi: 10.1016/j.jssc.2023.124108 (IF: 3,656).
Marquez, J.; Novikov, E.; Rigin, S.; Fonari, M.S.; Castañeda, R.; Kornilova, T.; Timofeeva, T.V. Exploiting Supramolecular Synthons in Cocrystals of Two Racetams with 4-Hydroxybenzoic Acid and 4-Hydroxybenzamide Coformers. Chemistry. 2023, 5(2), 1089—1100. Doi: 10.3390/chemistry5020074.
Lozovan, V.; Kravtsov, V.Ch.; Chumakov, Y.M.; Costriucova, N.V.; Siminel, N.; Petuhov, O.; Vlase, T.; Vlase, G.; Barba, A.; Fonari, M.S. Zn(II) and Cd(II) Metal–Organic Frameworks with Azine-Functionalized Pores: Crystal Structures, Photoluminescence, Solvent Exchange, and Molecular Simulations of Carbon Dioxide Binding Sites. Cryst Growth Des. 2023, 23(5), 3171—3185. Doi: 10.1021/acs.cgd.2c01345 (IF: 4,01).
Graur, V.; Usataia, I.; Graur, I.; Garbuz, O.; Bourosh, P.; Kravtsov, V.; Lozan-Tirsu, C.; Balan, G.; Fala, V.; Gulea, A. Novel Copper(II) Complexes with N⁴,S-Diallylisothiosemicarbazones as Potential Antibacterial/Anticancer Drugs. Inorganics. 2023, 11, 195-1—195-17. Doi: 10.3390/inorganics11050195 (IF: 3,149).
Graur, V.; Mardari, A.; Bourosh, P.; Kravtsov, V.; Usataia, I.; Ulchina, I.; Garbuz, O.; Gulea, A. Novel Antioxidants Based on Selected 3d Metal Coordination Compounds with 2-Hydroxybenzaldehyde 4,S-Diallylisothiosemicarbazone. Acta Chim Slov. 2023, 70(1), 122—130. Doi: 10.17344/acsi.2022.7885 (IF: 1,524).
Bulhac, I.; Ureche, D.; Kravtsov, V.; Bourosh, P. Synthesis and Structure of Heterometallic Compounds with Dimethyl Pyridine-2,6-dicarboxylate. Russ J Coord Chem. 2023, 49(2), 77—85. Doi: 10.1134/S1070328422700245 (IF: 1,814).
Булхак, И.; Уреке, Д.; Кравцов, И.; Боурош, П. Синтез и структура гетерометаллических соединений с 2,6-пиридиндиметилдикарбоксилатом. Координационная химия. 2023, 49(2), 101—110. Doi: 10.31857/S0132344X2270013X.
Bourosh, P.; Cocu, M.; Danilescu, O.; Bulhac, I. Binuclear Vanadium(V) Complex with the Ligand Based on Isonicotinic Acid Hydrazide and 1-Phenyl-1,3-Butanedione: Synthesis and Crystal Structure. Russ J Coord Chem. 2023, 49(4), 195—205. Doi: 10.1134/S1070328423700409 (IF: 1,814).
Боурош, П.; Коку, М.; Данилеску, О.; Булхак, И. Синтез и кристаллическая структура двухъядерного комплекса ванадия (V) с лигандом на основе гидразида изоникотиновой кислоты и 1-фенил-1,3-бутандиона. Координационная химия. 2023, 49(4), 195—204. Doi: 10.31857/S0132344X23700196.
Craciun, N.; Chisca, D.; Melnic, E.; Fonari, M.S. Unprecedented Coordination Compounds with 4,40-Diaminodiphenylethane as a Supramolecular Agent and Ditopic Ligand: Synthesis, Crystal Structures and Hirshfeld Surface Analysis. Crystals. 2023, 13(2), 289-1—289-14. Doi: 10.3390/cryst13020289 (IF: 2,67).
Colibaba, G.V.; Rusnac, D.; Costriucova, N.; Shikimaka, O.; Monaico, E.V. Low-temperature sintering of ZnO:Al ceramics by means of chemical vapor transport. J Mater Sci-Mater El. 2023, 34(2), 82. Doi: 10.1007/s10854-022-09458-1 (IF: 2,779).
Fonari, M.S.; Rigin, S.; Lesse, D.; Timofeeva, T.V. Co-crystals of polynuclear aromatic hydrocarbons and 9H-carbazole with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone acceptor: varieties in crystal packing, Hirshfeld surface analysis and quantum-chemical studies. J Mol Struct. 2023, 1278, 134900-1—134900-11. Doi: 10.1016/j.molstruc.2023.134900 (IF: 3,841).
Stati, D.; van Leusen, J.; Ahmed, N.; Kravtsov, V.Ch.; Kögerler, P.; Baca, S.G. A {Co^III₂Dy^III₄} Single-Molecule Magnet with an Expanded Core Structure. Cryst Growth Des. 2023, 23(1), 395—402. Doi 10.1021/acs.cgd.2c01085 (IF: 4,01).

Patents

Bulhac, I.; Ureche, D.; Ciloci, A.; Bouroș, P.; Tiurina, J.; Labliuc, S. Tetra(izotiocianat)cobaltat(II) de tris(dimetil piridin-2,6-dicarboxilat)stronţiu cu proprietăţi de stimulator al activităţii lipolitice la tulpina de fungi Rhizopus arrhizus CNMN FD 03. Brevet de Invenție nr. MD 4831 C1 2023.06.30.
Danilescu, O.; Bilhac, I.; Cocu, M.; Bouroș, P.; Ciloci, A.; Clapco, S.; Labliuc, S.; Dvornina, E. Perclorat de 2,6-diacetilpiridin-bis(picolinoilhidrazon)-bis(aqua)fier(III)-hidrat(1/2,5) cu proprietăţi de stimulator al sintezei lipazelor la tulpina de fungi Rhizopus arrhizus CNMN FD 03. Brevet de Invenție nr. MD 4874 B1 2023.11.30.
Bulhac, I.; Ureche, D.; Bouroș, P.; Cocu, M.; Ciloci, A.; Condruc, V.; Dvornina, E. Tris (2,6-dimetil piridindicarboxilat -1k ONO)-di-miu-(izotiocianat-1,2kN)...cu proprietăți de biostimulare al sintezei principiilor bioactive la fungi. Brevet de Invenție nr. MD 4847 C1 2023.09.30.
Bulhac, I.; Ureche, D.; Bouroș, P.; Cocu, M.; Ciloci, A.; Condruc, V.; Dvornina, E. Tetra(izotiuocianato) cobalt(II) de tris(dimetil piridin -2,6-dicarboxilat)calciu cu proprietăți de biostimulator al activității lipolitice pentru tulpina de fungi Rhizoppus arhizus CNMN FD 03. Brevet de Invenție nr. MD 4853 C1 2023.11.30.
Danilescu, O.; Bulhac, I.; Cocu, M.; Bouroş, P.; Ciloci, A.; Clapco, S.; Labliuc, S.; Matroi, A. Nitrat de 2,6-diacetilpiridin-bis(picolinoilhidrazon)-bis(aqua)fier(III)-hidrat(1/2,5) cu proprietăţi de stimulator al sintezei lipazelor la tulpina de fungi Rhizopus arrhizus CNMN FD 03 şi mediu nutritiv pentru cultivare. Brevet de Invenție nr. MD 4827 C1 2023.05.31.

2022

Ulchina, I.; Graur, V.; Tsapkov, V., Chumakov, Y.; Garbuz, O., Burduniuc, O.; Ceban, E.; Gulea, A. Introducing N-Heteroaromatic Bases into Copper(II) Thiosemicarbazon Complexes: A Way to Change their Biological Activity. ChemistryOpen. 2022, 11(12), e202200208-1—e2200074-7. Doi: 10.1002/open.202200208 (IF: 2,63).
Kondrotas, R.; Juškėnas, R., Krotkus, A.; Pakštas, V.; Suchodolskis, A.; Mekys, A.; Franckevičius, M.; Talaikis, M.; Muska, K.; Li, X.; Kauk-Kuusik, M., Kravtsov, V. Synthesis and physical characteristics of narrow bandgap chalcogenide SnZrSe₃. Open Research Europe. 2022, 2, 138-1—138-12. Doi: 10.12688/openreseurope.15168.1.
Ureche, D.; Bulhac, I.; Shova, S.; Bourosh, P. Novel Zn(II) binuclear and Ni(II) 1D polymeric coordinating compounds based on dianilineglyoxime and dicarboxylic acids: synthesis and structure. Chemistry Journal of Moldova. 2022, 17(2), 62—72. Doi:10.19261/cjm.2022.954.
Zveaghintseva, M.; Stingaci, E.; Pogrebnoi, S.; Lupascu, L.; Barba, A.; Duca, Gh.; Valica, V.; Uncu, L.; Kravtsov, V.; Terteac, D.; Brinzan, A.; Macaev, F. Resin acids as raw material for fabrication of antimicrobial micro- and nanoparticles of dehydroabietic acid loaded with cyclodextrin and chromenol hybrid. Chemistry Journal of Moldova. 2022, 17(2), 109—119. Doi: 10.19261/cjm.2022.942.

Rotari, N.; Coșcodan, E.; Chișca, D. Actual applications of infrared spectrophotometry in determining the quality of daily products. Acta et commentationes, Exact and Natural Sciences. 2022, 13(1), 31—39. Doi:13.36120/2587-3644.v13i1.31-39.
Danilescu, O.; Bourosh, P.; Kulikova, O.V.; Chumakov, Yu.M.; Bulhac, I.; Croitor, L. Dihydrazone Schiff base ligands – appropriate chemosensors for Cd (II) detection. Inorg Chem Commun. 2022, 146, 110199-1—110199-6. Doi: 10.1016/j.inoche.2022.110199 (IF: 3,428).
Darii, M.; Mikosch, A.; van Leusen, J.; Kravtsov, V.Ch.; Dvornina, E.G.; Clapco, S.T.; Ciloci, A.; Kögerler, P.; Baca, S.G. Fe^II/III and Mn^II complexes based on 2,4,6-tris(2-pyridyl)-triazine: synthesis, structures, magnetic and biological properties. RSC Adv. 2022, 12(45), 29034—29047. Doi: 10.1039/d2ra04868j (IF: 4,036).
Croitor, L.; Coropceanu, E.B.; Fonari, M.S. Anion–pyridine-n-oxime interplay to control metal–metal separations in a series of Cu(II) coordination polymers. CrystEngComm. 2022, 24(35), 6146—6154. Doi: 10.1039/D2CE01000C (IF: 3,756).
Lähderanta, E.; Hajdeu-Chicarosh, E., Kravtsov, V.; Shakhov, M.A.; Stamov, V.N.; Bodnar, I.; Arushanov, E.; Lisunov, K.G. Electronic properties of Cu₂(Zn,Cd)SnS₄ determined by the high-field magnetotransport. New J Phys. 2022, 24(9), 093008-1—093008-14. Doi: 10.1088/1367-2630/ac8b9f (IF: 3,716).
Podgornii, D.; Amombo Noa, F.M.; van Leusen, J.; McKenzie, Ch.J.; Öhrström, L.; Kögerler, P.; Baca, S.G. Heterometallic {Fe₁₈M₆} (M = Y, Gd, Dy) Pivalate Wheels Display Solvent-Induced Polymorphism. Cryst Growth Des. 2022, 22(9), 5526—5534. Doi: 10.1021/acs.cgd.2c00620 (IF: 4,01).
Gelmboldt, V.O.; Lytvynchuk, I.V.; Shyshkin, I.O.; Khromagina, L.N.; Fonari, M.S.; Kravtsov, V.Ch. Bis(2‐, 3‐, 4‐carboxyethylpyridinium) hexafluorosilicates as potential caries prophylactic agents. Arch Pharm. 2022, 355(7), e2200074-1—e2200074-16. Doi: 10.1002/ardp.202200074 (IF: 3,751).
Chumakov, Yu.; Danilescu, O.; Bourosh, P.; Kulikova, O.V.; Bulhac, I.; Croitor, L. Metal ions impact on the isostructurality and properties of 2D coordination polymers. CrystEngComm. 2022, 24, 4430—4439. Doi: 10.1039/d2ce00444e (IF: 3,545).
Darii, M.; Beleaev, E.S.; Kravtsov, V.Ch.; Bourosh, P., Chumakov, Y.; Hauser, J.; Decurtins, S.; Liu, Sh.-X.; Sultanova, O.; Baca, S.G. Crystalline multicomponent compounds involving hexaammine cobalt(III) cations. New J Chem. 2022, 46(23), 11404—11421. Doi: 10.1039/d2nj01655a (IF: 3,591).
Graur, V.; Chumakov, Yu.; Garbuz, O.; Hureau, Ch.; Tsapkov, V.; Gulea, A. Synthesis, Structure, and Biologic Activity of Some Copper, Nickel, Cobalt, and Zinc Complexes with 2-Formylpyridine N4-Allylthiosemicarbazone. Bioinorg Chem Appl. 2022, 2022, 2705332-1—2705332-18. Doi: 10.1155/2022/2705332 (IF: 7.778).

Chumakov, Yu.M.; Graur, V.O.; Ulchina, Ya.I.; Smaglii, V.A.; Gulea, A.P.; Garbuz, O.S.; Tsapkov, V.I. Crystal structures of [N′-(2- oxidobenzylidene)-N-(prop-2-en-1-yl)- carbamohydrazonothioato(2-)](1,10- phenanthroline) copper and [N′-(2- oxidobenzylidene)-N-(prop-2-en-1-yl)- carbamohydrazonothioato(2-)](2,2′- bipyridine) copper hemihydrates. J Struct Chem. 2022, 63(6), 905—913. Doi: 10.1134/S0022476622060075 (IF: 1,071).
Чумаков, Ю.М.; Граур, В.О.; Улькина, Я.И.; Смаглий, В.А.; Гуля, А.П.; Гарбуз, О.С.; Цапков, В.И. Кристаллические структуры гемигидратов [N’-(2-оксидобензилиден)-N-проп-2-ен-1-ил-карбамогидразонотиоато(2-)](1,10-фенантролин)меди и [N’-(2-оксидобензилиден)-N-проп-2-ен-1-ил-карбамогидразонотиофто(2-)](2,2’-бипиридин)меди. Журнал структурной химии. 2022, 63(6), 771—779. Doi:10.26902/JSC_id92728.
Croitor, L.; Petric, M.; Crisan, L.; Bourosh, P.N.; Vlase, G.; Vlase, T.; Crisan, M. Effect of substituents on the crystal structure and thermal stability of N-phosphorylated iminophosphoranes. J Therm Anal Calorim. 2022, 147(9), 5423—5435. Doi: 10.1007/s10973-022-11201-1 (IF: 4,626).
Croitor, L.; Vlase, G.; Vlase, T.; Bourosh, P.N.; Chumakov, Y.M.; Crisan, M. Relationship between crystal structure and thermal properties of polymorphic system methylethanolammonium 2‑chloro‑4‑nitrobenzoate. J Therm Anal Calorim. 2022, 147(9), 5437—5449. Doi: 10.1007/s10973-022-11263-1 (IF: 4,626).
Ramalingam, K.; Saravanan, M.; Bocelli, G.; Righi, L.; Chumakov, Y.; Cantoni, A. Pyrrolidinecarbodithioate as a planarity chuck in the search for cis-platin analogues of nickel: Spectral, single crystal X-ray structural, BVS, and CSM analysis of some planar nickel(II) mixed ligand complexes. Eur J Chem. 2022, 13(1), 117—125. Doi: 10.5155/eurjchem.13.1.117-125.2214.
Ureche, D.; Bulhac, I.; Shova, S.; Bourosh, P. Pseudomacrocyclic Bis(dianilineglyoximato)cobalt(III) Complex Cations: Synthesis and Structures. Russ J Coord Chem. 2022, 48(6), 333—343. Doi: 10.1134/S1070328422060070 (IF: 1,179).
Уреке, Д.; Булхак, И.; Шова, С.; Боурош, П. Синтез и структура псевдомакроциклических комплексных катионов бис(дианилинглиоксимато)кобальта(III). Координационная химия. 2022, 48(6), 323—333. Doi: 10.31857/S0132344X2206007X.
Duygulu, E.; Alev, O.; Chumakov, Y.; Öztürk, Z.Z.; Ayhan, M.M.; Yuksel, F. Morphology induced enhanced photoconductivity of a phthalocyanine-based benzimidazole linked two-dimensional conjugated covalent organic polymer. New J Chem. 2022, 46(13), 6314—6318. Doi:10.1039/D2NJ00339B (IF: 3,591).
Lozovan, V.; Kravtsov, V.Ch.; Costriucova, N.V.; Siminel, A.; Kulikova, O.V.; Fonari, M.S. Tunability in dimension, metal and ligand coordination modes and emission properties in Cd(II) and Zn(II) coordination networks based on 4,4’-(hydrazine-1,2-diyilidenebis(methanylylidene)) dibenzoic acid linker. J Solid State Chem. 2022, 310, 123021-1—123021-9. Doi: 10.1016/j.jssc.2022.123021 (IF: 3,498).
Danilescu, O.; Bulhac, I.; Bourosh, P.N.; Croitor, L. Anion-assisted Fe(III)-coordination supramolecular systems based on 2,6-diacetylpyridine dihydrazone. Polyhedron. 2022, 215, 115679-1—115679-12. Doi: 10.1016/j.poly.2022.115679 (IF: 3,052).
Bourosh, P.N.; Coropceanu, Ed.B.; Rija, A.P.; Ureche, D.; Ciloci, A.A.; Clapco, S.F.; Dvornina, E.G.; Labliuc, S.V.; Bulhac, I.I. Synthesis and Structures of Disulfanilamide Glyoxime and Ni(II) and Cu(II) Complexes with This Ligand Stimulating the Proteolytic Properties of [Cu(DsamH₂)₃]SO₄·5H₂O. Russ J Coord Chem. 2022, 48(1), 41—51. Doi: 10.1134/S1070328422010018 (IF: 1,179).
Боурош, П.Н.; Коропчану, Э.Б.; Рижа, А.П.; Уреке, Д.; Чилочи, А.А.; Клапко, С.Ф.; Дворнина, Е.Г.; Лаблюк, С.В.; Булхак, И.И. Cинтез и строение дисульфаниламидглиоксима и комплексных соединений Ni(II) и Cu(II) с этим лигандом. Стимулирующие протеолитические свойства [Cu(DsamH₂)₃]SO₄ · 5H₂O. Координационная химия. 2022, 48(1), 45—56. Doi: 10.31857/S0132344X22010017.
Çaydaşı, M.; Mintaş, M.F.; Chumakov, Y.M.; Volz, S.; Cengiz, A.; Seyidov, M.H.Y. A Study of Thermoelectric Performance of TlGaSe₂ Layered Dichalcogenides from First-Principles Calculations: Vacancy Defects Modeling and Engineering. Phys Status Solidi B. 2022, 259(1), 2100409-1—2100409-12. Doi: 10.1002/pssb.202100409 (IF: 1,710).

Crisan, M.; Petric, M.; Vlase, G.; Vlase, T.; Siminel, A.V.; Bourosh, P.N.; Croitor, L. Organic salt versus salt cocrystal: thermal behavior, structural and photoluminescence investigations. J Therm Anal Calorim. 2022, 147(2), 1203—1213. Doi: 10.1007/s10973-020-10438-y (IF: 4,626).
Colibaba, G.V.; Rusnac, D.; Fedorov, V.; Costriucova, N.; Monaico, E.V.; Potlog, T. Highly Conductive ZnO Thin Films Deposited Using CVT Ceramics as Magnetron Targets. În: ICNBME 2021, IFMBE Proceedings 87, 2022. 5th International Conference on Nanotechnologies and Biomedical Engineering, November 3–5, 2021, Chisinau, Moldova, p. 110—116. Doi: 10.1007/978-3-030-92328-0_15.
Colibaba, G.V.; Costriucova, N.; Rusnac, D.; Busuioc, S.; Monaico, E.V. Wettability of Highly Conductive ZnO:Ga:Cl CVT Ceramics with Various Ga Content. În: ICNBME 2021, IFMBE Proceedings 87, 2022. 5th International Conference on Nanotechnologies and Biomedical Engineering, November 3–5, 2021, Chisinau, Moldova, p. 610—616. Doi: 10.1007/978-3-030-92328-0_68.

Brevete de invenție / Patents
Lozovan V.; Fonari, M.; Kravţov, V.; Siminel, N.; Coropceanu, E.; Kulikova, O.; Costriucova, N. Polimer coordinativ unidimensional al cadmiului (II) în baza liganzilor 1,2-bis(piridin-4-ilmetilen)hidrazină şi acid 2-aminobenzoic, care manifestă activitate fotoluminescentă şi capacitate de schimb al moleculelor de solvent. Brevet de Invenție nr. MD 4776 B1 2021.11.30.
Ciloci, A.; Baca, S.;Clapco, S.; Tiurina, J.; Labliuc, S.; Dvornina, E.; Bivol, C.; Darii, M.; Kravţov, V. Aplicarea compusului coordinativ diaqua-nitrato-(2,4,6-tris(2-piridil)-s-triazină)-mangan(II) nitrat în calitate de stimulator al activităţii proteolitice la tulpina Fusarium gibbosum CNMN FD 12. Brevet de Invenție nr. MD 4803 C1 2022.11.30.

2021

Ureche, D.; Bulhac, I.; Ciocarlan, A.; Roshca, D.; Lupascu, L.; Bourosh, P. Novel vic-dioximes: synthesis, structure characterization, and antimicrobial activity evaluation. Turk J Chem. 2021, 45(6), 1873—1881. Doi: 10.3906/kim-2104-24 (IF: 1,236).

Baca, S.; Kögerler, P. Cluster-Based Coordination Polymers of Mn/Fe-Oxo Pivalates and Isobutyrates. Chemistry. 2021, 3(1), 314—326. Doi: 10.3390/chemistry3010023.
Baca, S.G.; Kogerler, P. Cluster-Based Coordination Polymers of Mn/Fe-Oxo Pivalates and Isobutyrates. În: Coordination Polymers and Metal-Organic Frameworks: Structures and Applications—A Themed Issue in Honor of Professor Christoph Janiak on the Occasion of His 60th Birthday. Ed. Catherine Housecroft, Basel: MDPI, 2021. 5—18 p. ISBN 978-3-0365-1959-3. Doi: 10.3390/books978-3-0365-1959-3.
Витиу, А.; Коропчану, Э.; Боурош, П. Координационные соединения переходных металлов с роданин-3-уксусной кислотой. Координационная химия. 2021, 47(11), 655—667. Doi: 10.31857/S0132344X21110062.
Vitiu, A.; Coropceanu, E.; Bourosh, P. Coordination Compounds of Transition Metals with Rhodanine-3-acetic Acid. Russ J Coord Chem. 2021, 47(11), 717—729. Doi 10.1134/S1070328421110063 (IF: 1,179).
Gorobet, A.; Crisan, M.E.; Bourosh, P.N.; Croitor, L. Structural investigation and hirshfeld surface analysis of Cu(II) triethanolamine 4-nitrobenzoate. Rev Roum Chim. 2021, 66(4), 355—359. Doi: 10.33224/rrch.2021.66.4.06 (IF: 0,279).
Özcan, E.; Dedeoglu, B.; Chumakov, Y.; Zorlu, Y.; Çoșut, B.; Ayhan, M.M. Modulation of supramolecular self-assembly of BODIPY tectons via halogen bonding. CrystEngComm. 2021, 23(36), 6365—6375. Doi: 10.1039/D1CE00862E (IF: 3,545).

Chisca, D.; Croitor, L.; Coropceanu, E.B.; Fonari, M.S. Four Cu(II) coordination polymers with biocompatible isonicotinamide and picolinate ligands in interplay with anionic and neutral linkers. Inorg Chem Commun. 2021, 132, 108864-1—108864-10. Doi: 10.1016/j.inoche.2021.108864 (IF: 2,495).
Podgornii, D.; van Leusen, J.; Kravtsov, V.Ch.; Kögerler, P.; Baca, S.G. A {Na₂Fe₁₀} isobutyrate cluster, interlinked into 1D chains. CrystEngComm. 2021, 23(30), 5153—5156. Doi: 10.1039/d1ce00777g (IF: 3,545).
Zveaghintseva, M.; Stingaci, E.; Pogrebnoi, S.; Smetanscaia, A.; Valica, V.; Uncu, L.; Kravtsov, V.; Melnic, E.; Petrou, A.; Glamoclija, J.; Sokovic, M.; Carazo, A.; Mladenka, P.; Poroikov, V.; Geronikaki, A.; Macaev, F.Z. Chromenol Derivatives as Novel Antifungal Agents: Synthesis, In Silico and In Vitro Evaluation. Molecules. 2021, 26(14), 4304-1—4304-20. Doi: 10.3390/molecules26144304 (IF: 4,411).

Fonari, M.S.; Kravtsov, V.Ch.; Bold, V.; Lucenti, E.; Cariati, E.; Marinotto, D.; Forni, A. Structural Landscape of Zn(II) and Cd(II) Coordination Compounds with Two Isomeric Triimidazole Luminophores: Impact of Crystal Packing Patterns on Emission Properties. Cryst Growth Des. 2021, 21(7), 4184—4200. Doi: 10.1021/acs.cgd.1c00459 (IF: 4,089).
Куба, Л.Н.; Горинчой, Е.К.; Драганча, Д.П.; Шова, С.Г.; Боурош, П.Н. Нековалентные взаимодействия в архитектурах с семикарбазонами замещенного салицилового альдегида. Координационная химия. 2021, 47(7), 439—452. Doi: 10.31857/S0132344X21070033.
Cuba, L.N.; Gorincioi, E.C.; Dragancea, D.P.; Shova, S.G.; Bourosh, P.N. Noncovalent Interactions in the Architectures with Substituted Salicylaldehyde Semicarbazones. Russ J Coord Chem. 2021, 47(7), 488—501. Doi: 10.1134/S1070328421070034 (IF: 0,973).
KostakoÄŸlu, S.T.; Chumakov, Yu.; Zorlu, Yu.; Sadak, A.E.; Denizalti, S.; Gürek, A.G.; Ayhan, M.M. Elucidating the role of non-covalent interactions in unexpectedly high and selective CO₂ uptake and catalytic conversion of porphyrin-based ionic organic polymers. Mater Advances. 2021, 2(11), 3685—3694. Doi: 10.1039/d1ma00217a.
Croitor, L.; Cocu, M.; Bulhac, I.; Bourosh, P.N.; Kravtsov, V.C.; Petuhov, O.; Danilescu, O. Evolution from discrete mononuclear complexes to trinuclear linear cluster and 2D coordination polymers of Mn(II) with dihydrazone Schiff bases: preparation, structure and thermal behavior. Polyhedron. 2021, 206, 115329. Doi: 10.1016/j.poly.2021.115329 (IF: 2,343).
Melnic, E.; Kravtsov, V.Ch.; Lucenti, E.; Cariati, E.; Forni, A.; Siminel, N.; Fonari, M.S. Regulation of π···π stacking interactions between triimidazole luminophores and comprehensive emission quenching by coordination to Cu(II). New J Chem. 2021, 45(20), 9040—9052. Doi: 10.1039/d1nj00909e (IF: 3,288).
Caimac, N.; Melnic, E.; Chisca, D.; Fonari, M.S. 2,4-Diamino-6-phenyl-1,3,5-triazin-1-ium nitrate: intriguing crystal structure with high Z′/Z″ and hydrogen bond numbers and Hirshfeld surface analysis of intermolecular interactions. CrystEngComm. 2021, 23(17), 3099—33108. Doi: 10.1039/d1ce00313e (IF: 3,117).
Danilescu, O.; Bourosh, P.N.; Petuhov, O.; Kulikova, O.V.; Bulhac, I.; Chumakov, Yu.M.; Croitor, L. Crystal Engineering of Schiff Base Zn(II) and Cd(II) Homoand Zn(II)M(II) (M = Mn or Cd) Heterometallic Coordination Polymers and Their Ability to Accommodate Solvent Guest Molecules. Molecules. 2021, 26(8), 2317-1—2317-15. Doi: 10.3390/molecules26082317 (IF: 3,267).
Baca, S.G.; Herringer, S.; Liu, Sh.-X.; Decurtins, S. Polynuclear Clusters Based on Fe/Fe-Ln Carboxylates with Selected Magnetic Properties. În: Comprehensive Coordination Chemistry III (Third Edition). Ed. E.C.Constable, G.Parkin, L.Que Jr., 2021, p. 29-65. ISBN: 978-0-08-102689-2. Doi: 10.1016/B978-0-08-102688-5.00030-1.
Ayhan, M.M.; Özcan, E.; Dedeoglu, B.; Chumakov, Yu.; Zorlu, Y.; Coșuta, B. Carbon (sp³) tetrel bonding mediated BODIPY supramolecular assembly: Via unprecedented synergy of C_sp3â‹¯N and C_sp3â‹¯F pair interactions. CrystEngComm. 2021, 23(2), 268—272. Doi: 10.1039/d0ce01640c (IF: 3,117).
Graur, V.; Usataia, I.; Bourosh, P.; Kravtsov, V.; Garbuz, O.; Hureau, Ch.; Gulea, A. Synthesis, characterization, and biological activity of novel 3d metal coordination compounds with 2â€acetylpyridine N⁴â€allylâ€Sâ€methylisothiosemicarbazone. Appl Organomet Chem. 2021, 35(4), e6172. Doi: 10.1002/aoc.6172 (IF: 3,140).
Sumalan, R.; Halip, L.; Maffei, M.; Croitor, L.; Siminel, A.V.; Radulov, I.; Sumalan, R.M.; Crisan, M.E. Bioprospecting Fluorescent Plant Growth Regulators from Arabidopsis to Vegetable Crops. Int J Mol Sci. 2021, 22(6), 2797-1—2797-16. Doi: 10.3390/ijms22062797 (IF: 4,556).
Коропчану, Э.Б.; Уреке, Д.; Рижа, А.П.; Чилочи, А.А.; Клапко, С.Ф.; Дворнина, Е.Г.; Булхак, И.И.; Коку, М.; Боурош, П.Н. Synthesis and Structures of Nickel(II) Complexes Based on Dianilineglyoxime. Stimulation of the Proteolytic Properties by [Ni(DAnH)2]·0.25H2O. Координационная химия. 2021, 47(1), 21—29. Doi: 10.31857/S0132344X21010023.
Coropceanu, E.B.; Ureche, D.; Rija, A.P.; Ciloci, A.A.; Clapco, S.F.; Dvornina, E.G.; Bulhac, I.I.; Cocu, M.; Bourosh, P.N. Synthesis and Structures of Nickel(II) Complexes Based on Dianilineglyoxime. Stimulation of the Proteolytic Properties by [Ni(DAnH)₂]·0.25H₂O. Russ J Coord Chem. 2021, 47(1), 17—25. Doi: 10.1134/S1070328421010024 (IF: 0,973).
Гуля, А.П.; Граур, В.О.; Улькина, Я.И.; Боурош, П.Н.; Смаглий, B.A.; Гарбуз, О.С.; Цапков, В.И. Synthesis, Structure, and Biological Activity of Mixed-Ligand Amine-Containing Copper(II) Coordination Compounds with 2-(2-Hydroxybenzylidene)-N-(prop-2-en-1-yl)hydrazinecarbothioamide. Журнал Общей Химии. 2021, 91(1), 125—135. Doi: 10.31857/S0044460X21010133.
Gulea, А.P.; Graur, V.О.; Ulchina, Ia.I.; Bourosh, P.N.; Smaglii, V.A.; Garbuz, O.S.; Tsapkov, V.I. Synthesis, Structure, and Biological Activity of Mixed-Ligand Amine-Containing Copper(II) Coordination Compounds with 2-(2-Hydroxybenzylidene)-N-(prop-2-en-1-yl)hydrazinecarbothioamide. Russ J Gen Chem. 2021, 91(1), 98—107. Doi: 10.1134/S1070363221010114 (IF: 0,716).
Baca, S.G.; Amombo Noa, F.M.; Öhrström, L. Octanuclear heterometallic Fe^III-Ce^IV pivalate clusters: From a close {Fe₄Ce₄(μ₄-O)₄} cage to an open {Fe₄Ce₄(μ₄-O)₂(μ₃-O)₂} core. Inorg Chim Acta. 2021, 515, 120038-1—120038-6. Doi: 10.1016/j.ica.2020.120038 (IF: 2,304).
Colibaba, G.V.; Rusnac, D.; Fedorov, V.; Petrenko, P.; Monaico, E.V. Low-temperature sintering of highly conductive ZnO:Ga:Cl ceramics by means of chemical vapor transport. J Eur Ceram Soc. 2021, 41(1), 443—450. Doi: 10.1016/j.jeurceramsoc.2020.08.002 (IF: 4,495).
Gorobet, A.; Crisan, M.E.; Bourosh, P.N.; Siminel, A.V.; Croitor, L. Supramolecular architectures and photoluminescent properties of triethanolammonium 4-nitrobenzoate salt and its Ni(II) complexes. Polyhedron. 2021, 193, 114893. Doi: 10.1016/j.poly.2020.114893 (IF: 2,343).

Brevete de invenție/Patents

Gologan, V.; Sidelnicova, S.; Ivașcu, S.; Volodina, G. Procedeu de depunere a acoperirilor din electrolit pe bază de crom trivalent. Brevet de Invenție nr. MD 4720 C1 2021.05.31.
Baca, S.; Sultanova, O.; Darii, M.; Bouroș, P. Compusul coordinativ hexaamincobalt(III) triclorură bis(1,10-fenantrolină) trihidrat cu proprietăți de inhibitor al dezvoltării cancerului la viță de vie. Brevet de Invenție nr. MD 4725 C1 2021.06.30.
Baca, S.; Darii, M.; Kravțov, V.; Ciloci, A.; Tiurina, J.; Labliuc, S.; Dvornina, E.; Bivol, C.; Clapco, S. Compus coordinativ izobutirato-cloro-metoxo-(2,4,6-tris(2-piridil)-s-triazină)-mangan(II) metanol solvat care manifestă proprietăți de stimulator al activității proteolitice la tulpina Fusarium gibbosum CNMN FD 12. Brevet de Invenție nr. MD 4724 C1 2021.06.30.
Ureche, D.; Bulhac, I.; Veveriță, A.; Bouroș, P.; Lupașcu, L. Compusul 2,5,11,14-tetraazatriciclo-[13,3,1,16,10]-icosa-1(19),6,8,10(20),15,17-hexaen-3,4,12,13-tetraontetraoximă bis(N,N-dimetilformamidă) cu activitate antibacteriană și antifungică. Brevet de Invenție nr. MD 4745 B1 2021.02.28.
Ureche, D.; Bulhac, I.; Bouroș, P.; Roșca, D.; Lupașcu, L. Bis-(N,N'-bis(4-tolil)diaminoglioximă)-4-metilanilin-trihidrat pentru utilizare în calitate de remediu antibacterian în agricultură. Brevet de Invenție nr. MD 4762 B1 din 2021.07.31.
Baca, S.; Sultanova, O. Utilizarea 1, 10 fenatrolina ca inhibitor al dezvoltării cancerului la vița de vie. Brevet de Invenție nr. MD 1459 Z din 2021.05.31.

2020

Rusnac, R.; Botnaru, M.; Barba, N.; Petrenko, P.; Chumakov, Y.; Gulea, A. Compounds removed from the condensation reaction between 2-acetylpyridine and 2-formylpyridine. synthesis, crystal structure and biological evaluation. Chemistry Journal of Moldova. 2020, 15(2), 88—98. Doi: 10.19261/cjm.2020.695.
Gulea, А.P.; Graur, V.О.; Diurici, E.C., Ulchina, Ia.I.; Bourosh, P.N.; Balan, G.G.; Burduniuc, O.S.; Tsapkov, V.I.; Rudic, V.F. Synthesis, Structure, and Biological Activity of Copper(II), Nickel(II), Cobalt(III), and Iron(III) Coordination Compounds with 2-{2-[(Prop-2-en-1-yl)carbamothioyl]hydrazinylidene}propanoic Acid. Russ J Gen Chem. 2020, 90(11), 2120—2127. Doi: 10.1134/S107036322011016X (IF: 0,716).
Kravtsov, V.Ch.; Lozovan, V.; Siminel, N.; Coropceanu, E.B.; Kulikova, O.V.; Costriucova, N.V.; Fonari, M.S. From 1D to 2D Cd(II) and Zn(II) Coordination Networks by Replacing Monocarboxylate with Dicarboxylates in Partnership with Azine Ligands: Synthesis, Crystal Structures, Inclusion, and Emission Properties. Molecules. 2020, 25, 5616-1—5616-20. Doi: 10.3390/molecules25235616 (IF: 3,267).
Chisca, D.; Croitor, L.; Melnic, E.; Petuhov, O.; Kulikova, O.; Fonari, M.S. Six transition metal–organic materials with the ditopic 4,40-diaminodiphenylmethane ligand: Synthesis, structure, characterization and luminescent properties. Polyhedron. 2020, 192, 114844-1—114844-10. Doi: 10.1016/j.poly.2020.114844 (IF: 2,343).
Danilescu, O.; Bulhac, I.; Shova, S.; Novitchi, G.; Bourosh, P. Coordination Compound of Copper(II) with Schiff Bases Based on Aromatic Carbonyl Compounds and Hydrazides of Carboxylic Acids: Synthesis, Structures, and Properties. Russ J Coord Chem. 2020, 46(12), 838—849. Doi: 10.1134/S1070328420090018 (IF: 0,973).
Ureche, D.; Rija, A.; Bulhac, I.; Coropceanu, E.; Bourosh, P. Synthesis and Structural Study of 2D Coordination Polymers of Zn(II), Cd(II) and Mn(II) Based on Diaminobenzoylglyoxime. Russ J Inorg Chem. 2020, 65(12), 1838—1847. Doi 10.1134/S0036023620120189 (IF: 0,940).
Croitor, L.; Crisan, M.; Vlase, G.; Vlase, T.; Bodnarescu, F.; Sumalan, R.; Petric, M.; Siminel, A.V.; Bourosh, P. Advances in new multicomponent crystal system: structure, thermal kinetic analysis, photoluminescent, and biological activity investigations. J Therm Anal Calorim. 2020, 142(1), 191—201. Doi: 10.1007/s10973-020-09524-y (IF: 2,731).
Chumakov, Y.; Bayram, G. Theoretical Study of Thermoelectric Properties of Covalent Organic Frameworks with Slipped Arrangement. J Electron Mater. 2020, 49(9), 5498—5507. Doi: 10.1007/s11664-020-08287-4 (IF: 1,774).
Lozovan, V., Kravtsov, V.Ch.; Coropceanu, E.B.; Siminel, N.; Kulikova, O.V.; Costriucova, N.V.; Fonari, M.S. Seven Zn(II) and Cd(II) 1D coordination polymers based on azine donor linkers and decorated with 2-thiophenecarboxylate: Syntheses, structural parallels, Hirshfeld surface analysis, and spectroscopic and inclusion properties. Polyhedron. 2020, 188, 114702-1—114702-12. Doi: 10.1016/j.poly.2020.114702 (IF: 2,284).
Crisan, M.E.; Vlase, G.; Vlase, T.; Croitor, L.; Ilia, Gh.; Bourosh, P.N.; Kravtsov, V.Ch.; Petric, M.F. Thermogravimetric and kinetic study of new bis(iminophosphorane)ethane solvates. J Therm Anal Calorim. 2020, 141(3), 1009—1016. Doi: 10.1007/s10973-020-09628-5 (IF: 2,471).
Croitor, L.; Petric, M.F.; Vlase, G.; Vlase, T.; Siminel, A.V.; Bourosh, P.N.; Crisan, M.E. The solvent effect in obtaining of acid–base multicomponent systems: thermal, structural and luminescence study. J Therm Anal Calorim. 2020, 141(3), 973—979. Doi: 10.1007/s10973-020-09633-8 (IF: 2,471).

Gulea, А.P.; Usataia, I.S.; Graur, V.О.; Chumakov, Yu.M.; Petrenko, P.A.; Balan, G.G.; Burduniuc, O.S.; Tsapkov, V.I.; Rudic, V.F. Synthesis, Structure and Biological Activity of Coordination Compounds of Copper, Nickel, Cobalt, and Iron with Ethyl N'-(2-Hydroxybenzylidene)-N-prop-2-en-1-ylcarbamohydrazonothioate. Russ J Gen Chem. 2020, 90(4), 630—639. Doi: 10.1134/S107036322004012X (IF: 0,643).
Stingaci, E.; Zveaghinteva, M.; Pogrebnoi, S.; Lupascu, L.; Valica, V.; Uncu, L.; Smetanscaia, A.; Drumea, M.; Petrou, A.; Ciric, A.; Glamoclija, J.; Sokovic, M.; Kravtsov, V.; Geronikaki, A.; Macaev, F. New vinyl-1,2,4-triazole derivatives as antimicrobial agents: Synthesis, biological evaluation and molecular docking studies. Bioorg Med Chem Lett. 2020, 30(17), 127368-1—127368-7. Doi: 10.1016/j.bmcl.2020.127368 (IF: 2,448).
Gelmboldt, V.O.; Shyshkin, I.O.; Anisimov, V.Yu.; Fonari, M.S.; Kravtsov, V.Ch. Bis(3-hydroxymethylpyridynium) hexafluorosilicate monohydrate as a new potential anticaries agent: Synthesis, crystal structure and pharmacological properties. J Fluorine Chem. 2020, 235, 109547-1—109547-5. Doi: 10.1016/j.jfluchem.2020.109547 (IF: 2,055).
Sumalan, R.L.; Croitor, L.; Petric, M.; Radulov, I.; Bourosh, P.; Sumalan, R.M.; Crisan, M. p-Aminobenzoate Organic Salts as Potential Plant Growth Regulators for Tomatoes. Molecules. 2020, 25(7), 1635-1—1635-15. Doi: 10.3390/molecules25071635 (IF: 3,060).
Gulea, А.P.; Graur, V.О.; Chumakov, Yu.M.; Petrenko, P.A.; Garbuz, О.S.; Tsapkov, V.I.; Gudumac, V.S. Nickel(II) Complexes with Pentane-2,4-Dione Bis(4-Allylthiosemicarbazone). Russ J Gen Chem. 2020, 90(1), 111—117. Doi: 10.1134/S107036322001017X (IF: 0,643).
Lozovan, V.; Kravtsov, V.Ch.; Coropceanu, E.B.; Siminel, A.V.; Kulikova, O.V.; Costriucova, N.V.; Fonari, M.S. Water-sulfate anion interplay in the evolution of solid state architectures and emission properties of Zn and Cd coordination networks with four azine ligands. J Solid State Chem. 2020, 286, 121312-1—121312-15. Doi: 10.1016/j.jssc.2020.121312 (IF: 2,291).
Croitori, D.; Filippova, I.; Kravtsov, V.; Günther, A.; Widmann, S.; Reuter, D.; Krug von Nidda, H.-A.; Deisenhofer, J.; Loidl, A.; Tsurkan, V. Structure, superconductivity, and magnetism in Rb_1−xFe_1.6Se_2−zS_z. Phys Rev B. 2020, 101(5), 054516-1—054516-18. Doi: 10.1103/PhysRevB.101.054516 (IF: 3,736).
Lozan, V.; Makhloufi, G.; Druta, V.; Bourosh, P.; Kravtsov, V.; Ch.; Marangoci, N.; Heering, Ch.; Janiak, Ch. Synthesis and structure of zinc(II) and cobalt(II) coordination polymers involving the elongated 2′,3′,5′,6′ tetramethylterphenyl-4, 4″-dicarboxylate ligand. Inorg Chim Acta. 2020, 506, 119500-1—119500-9. Doi: 10.1016/j.ica.2020.119500 (IF: 2,433).
Lozovan, V.; Kravtsov, V.Ch.; Gorincioi, E.; Rotaru, A.; Coropceanu, E.B.; Siminel, N.; Fonari, M. Chromism, positional, conformational and structural isomerism in a series of Zn(II) and Cd(II) coordination polymers based on methylated azine N,N0-donor linkers. Polyhedron. 2020, 180, 114411-1—114411-12. Doi: 10.1016/j.poly.2020.114411 (IF: 2,284).
Balan,G.; Burduniuc, O.; Usataia, I.; Graur, V.; Chumakov, Y.; Petrenko, P.; Gudumac, V.; Gulea, A.; Pahontu, E. Novel 2-formylpyridine 4-allyl-Smethylisothiosemicarbazone and Zn(II), Cu(II), Ni(II) and Co(III) complexes: Synthesis, characterization, crystal structure, antioxidant, antimicrobial and antiproliferative activity. Appl Organomet Chem. 2020, 34(3), e5423-1—e5423-17. Doi: 10.1002/aoc.5423 (IF: 3,259).
Darii, M.; Kravtsov, V.Ch.; Krämer, K.; Hauser, J.; Decurtins, S.; Liu, S.-X.; Affronte, M.; Baca, S.G. Aggregation of a Giant Bean-like {Mn₂₆Dy₆} Heterometallic Oxo-Hydroxo-Carboxylate Nanosized Cluster from a Hexanuclear {Mn₆} Precursor. Cryst Growth Des. 2020, 20(1), 33—38. Doi: 10.1021/acs.cgd.9b01333 (IF: 4,153).
Vitiu, A.; Chișca, D.; Gorincioi, E.; Coropceanu, E.; Bourosh, P. Synthesis and Biological Properties of the Novel Coordination Compound with Rhodanine-3-Acetic Acid. În: IFMBE Proceedings, V. 77, Springer, 2020, p. 713—717. Doi: 10.1007/978-3-030-31866-6_126.

Brevete de invenție/Patents

Parșutin, V.; Cernîșeva, N.; Covali, A.; Baca, S.; Kravțov, V.; Stati, D. Inhibitor de coroziune a oțelului în apă. Brevet de Invenție nr. MD 1427 Z 2020.12.31.
Baca, S.; Darii, M.: Kravțov, V.; Ciloci, A., Tiurina, J.; Labliuc, S.; Dvornina, E.; Bivol, C.; Clapco, S. Compus coordinativ izobutirato-cloro-metoxo-(2,4,6-tris(2-piridil)-s-triazină)-mangan(II) metanol solvat care manifestă proprietăți de stimulator al activității proteolitice la tulpina Fusarium gibbosum CNMN FD 12. Brevet de Invenție nr. MD 4724 B1 2020.11.30.
Baca, S.; Sultanova, O.; Darii, M.; Bouroș, P. Compusul coordinativ hexaamincobalt(III) triclorură bis(1,10-fenantrolină) trihidrat cu proprietăți de inhibitor al dezvoltării cancerului la viță de vie . Brevet de Invenție nr. MD 4725 B1 2020.11.30.
Baca, S.; Sultanova, O. Aplicarea compusului 1,10-fenantrolină în calitate de inhibitor al dezvoltării cancerului la viță de vie. Brevet de Invenție nr. MD 1459 Y 2020.10.31.
Vitiu, A.; Chișca, D.; Gorincioi, E.; Coropceanu, E.; Bouroș, P. Compus coordinativ polimeric al zincului cu ligand nou obținut prin condensare, care manifestă activitate antifungică și antibacteriană. Brevet de invenție MD 4640 C1 2020.02.29.
Melnic, E.; Kravțov, V.; Baca, S. Procedeu de obținere a c ompus ului coordinativ al cuprului(II): bis(µ 2 -1-(7-cloro-6-metil-2,3-bis(piridin-2-il)-5H-ciclopenta[b] pirazin-5-il)etanonă)-dicloro-di-cupru(II) metanol solvat. Brenet de invenție MD 4653 B1 2019.10.31.
Ciloci, A.; Baca, S.; Tiurina, J.; Labliuc, S.; Dvornina, E.; Bivol, C.; Clapco, S.; Darii, M.; Kravțov, V. Mediu nutritiv pentru cultivarea tulpinii de fungi Trichoderma koningii Oudemans CNMN FD 15 - producătoare de proteaze neutre. Brevet de invenție MD 4654 B1 2019.10.31.
Danilescu, O.; Bouroș, P.; Petuhov, O.; Bulhac, I.; Șova, S. Polimer coordinativ 2,6-diacetilpiridinbis(izonicotinoilhidrazonato)(2-)cobalt(II)â”€apă(1/5,75) care manifestăproprietăți adsorbtive. Brevet de Invenție MD 4672 B1 2020.01.31.
Darii, M.; Kravțov, V.; Baca, S. Compuși coordinativi dotriacontanucleari heterometalici ai oxi-hidroxi-izobutiraților de mangan cu lantanide și procedeu de obținere a acestora. Brevet de Invenție nr. MD 4660 C1 2020.06.30.

2019

Melnic, E.; Kravtsov, V.; Lucenti, E.; Cariati, E.; Forni, A.; Fonari, M. Structural landscape of Cu^II coordination compounds with isomers and derivatives of cyclic triimidazole. Acta Crystallogr A. 2019, A75(part a2), e502. Doi: 10.1107/S2053273319090545 (IF: 1,878).
Kravtsov, V.; Bold, V.; Chisca, D.; Lucenti, E.; Cariati, E.; Forni, A.; Fonari, M. Crystallographic evidence for aggregation patterns of two cyclic triimidazole phosphors in Zn^II and Cd^II complexes. Acta Crystallogr A. 2019, A75(part a2), e572. Doi: 10.1107/S2053273319089848 (IF: 1,878).
Darii, M. A hexanuclear Mn(II, III) pivalate cluster with a {Mn₆O₂} core. Mold J Phys Sci. 2019, 18(1-4), 59—64. ISSN 1810-648X.
Okumuș, E.; Öztürk, S.T.; Chumakov, Yu.M.; Nadjafov, A.I.; Mamedov, N.T.; Mammadov, T.G.; Wakita, K.; Shim, Y.-G.; Mikailzade, F.A.; Seyidov, M.H.Yu. Identification of Mn dopant in the structure of TlInS₂ layered semiconductor. Mater Res Express. 2019, 6(5), 056110-1—056110-11. Doi: 10.1088/2053-1591/ab063e (IF: 1,449).
Ureche, D.; Bulhac, I.; Rija, A.; Coropceanu, E.; Bourosh, P. Dianilineglyoxime Salt and Its Binuclear Zn(II) and Mn(II) Complexes with 1,3-Benzenedicarboxylic Acid: Synthesis and Structures. Russ J Coord Chem 2019 45(12), 843—855. Doi: 10.1134/S107032841912008X (IF: 0,636).
Dasari, R.R.; Wang, X.; Wiscons, R.A.; Haneef, H.F.; Ashokan, A., Zhang, Y.; Fonari, M.S.; Barlow, S.; Coropceanu, V.; Timofeeva, T.V.; Jurchescu, O.D.; Brédas, J.-L.C.; Matzger, A.J.; Marder, S.R. Charge-Transport Properties of F6TNAP-Based Charge-Transfer Cocrystals. Adv Funct Mater. 2019, 29(49), 1904858-1—1904858-12. Doi: 10.1002/adfm.201904858 (IF: 15,621).
Gorinchoy, V.; Cuzan-Munteanu, O.; Petuhov, O.; Melnic, E.; Kravtsov, V.Ch.; Shova, S. Thermal analysis, synthesis and structural studies of heterometallic {Fe₂MO} salicylate complexes. J Therm Anal Calorim. 2019, 138(4), 2623—2633. Doi: 10.1007/s10973-019-08642-6 (IF: 2,471).
Aksakal, N.E.; Chumakov, Yu.; Yuksel, F. Crystal Structures of Two Perylenediimides: A Study of Bay-Substitution. J Chem Crystallogr. 2019, 49(2), 72—79. Doi: 10.1007/s10870-018-0735-1 (IF: 0,630).
Vitiu, A.A.; Coropceanu, E.B.; Bourosh, P.N. New Сu(II) and Co(II) Complexes with 2-Benzoylpyridine: Syntheses and Crystal Structures. Russ J Coord Chem. 2019, 45(11), 804—808. Doi: 10.1134/S1070328419110101 (IF: 0,636).
Croitor, L.; Petric, M.F.; Szerb, E.I.; Vlase, G.; Bourosh, P.N.; Chumakov, Y.M.; Crisan, M.E The role of 4-nitrobenzoic acid polymorphs in the crystallization process of organic acid–base multicomponent systems. Crystengcomm. 2019, 21(40), 6038—6047. Doi: 10.1039/c9ce01239g (IF: 3,382).
Zelentsov, V.I.; Datsko, T.Ya.; Politova, E.D.; Volodina, G.F.; Smolyanskii, A.S. Preparation and Properties of an Aluminum Hydroxide-Modified Diatomite Sorbent for Removal of Fluorides from Waters. Surf Eng Appl Elect. 2020, 55(4), 455—462. Doi: 10.3103/S1068375519040161.
Gulea, А.P.; Mitkevich, N.L.; Chumakov, Yu.M.; Petrenko, P.A.; Balan, G.G.; Burduniuc, O.S.; Tsapkov, V.I. Synthesis, Structure, and Biological Activity of Coordination Compounds of Cobalt(II), Nickel(II), and Copper(II) with N-(Methoxyphenyl)-2-[(5-nitrofuryl)methylene]hydrazine Carbothioamides. Russ J Gen Chem. 2019, 89(7), 1415—1423. Doi: 10.1134/S1070363219070119 (IF: 0,643).
Crisan, M.E.; Gorobet, A.; Siminel, A.V.; Bourosh, P.N.; Croitor, L. A new supramolecular isomer of p-aminobenzoate Zn(II) coordination polymer: Structure and photoluminescent property. Polyhedron. 2019, 171, 502—507. Doi: 10.1016/j.poly.2019.07.042 (IF: 2,284).
Chumakov, Yu.M.; Mintaș, M.F.; Amiraslanov, I.R.; Volz, S., Mammadov, S.N.; Mamedov, N.T.; Mammadov, T.G.; Ishikawa, M.; Wakita, K.; Seyidov, M.H.Yu. Synthesis, Powder Xâ€Ray Diffraction, and Ab Initio Study of TlInSe₂: Analysis of Its Thermoelectric Properties . Phys Status Solidi A. 2019, 216(15), 1800835-1—1800835-10. Doi: 10.1002/pssa.201800835 (IF: 1,606).
Gelmboldt, V.O.; Shyshkin, I.O.; Fonari, M.S.; Kravtsov, V.Kh. Synthesis, crystal structure, and some properties of 4-hydroxymethylpyridinium hexafluorosilicate. J Struct Chem. 2019, 60(7), 1150—1155. Doi: 10.1134/S0022476619070175 (IF: 0,541).
Vitiu, A. Novel iron(II) and copper(II) polymeric coordination compounds with n,n′-bipyridine-type ligands: synthesis and characterization. Chem J Mold. 2019, 14(1), 120—127. Doi: 10.19261/cjm.2019.569.
Gulea, A.P.; Graur, V.O.; Chumakov, Yu.M.; Petrenko, P.A.; Balan, G.G.; Burduniuc, O.S.; Tsapkov, V.I.; Rudic, V.F. Synthesis, Structure, and Biological Activity of Copper and Cobalt Coordination Compounds with Substituted 2-(2-Hydroxybenzylidene)-N-(prop-2-en-1-yl)hydrazinecarbothioamides. Russ J Gen Chem. 2019, 89(5), 953—964. Doi: 10.1134/S1070363219050153 (IF: 0,658).
Chisca, D.; Siminel, A.V.; Fonari, M.S.; Croitor, L. Structural characterization and emission properties of mixed-ligand transition metal coordination complexes with dicarboxylic acids and pyrazinecarboxamide. Polyhedron. 2019, 170, 245—252. Doi: 10.1016/j.poly.2019.05.052 (IF: 2,067).
Rigin, S.; Armijo, B.; Krivoshein, A.V.; Fonari, M.; Timofeeva, T. Crystal structure and Hirshfeld surface analysis of new polymorph of racemic 2-phenylbutyramide. Acta Crystallogr E. 2019, E75, 826—829. Doi: 10.1107/S2056989019007011.
Botezat, O.; van Leusen, J.; Kogerler, P.; Baca, S.G. Ultrasound-Assisted Formation of {Fe₆Ln/Y₄} Wheel-Shaped Clusters and Condensed {Fe₄Ln/Y₂} Aggregates. Eur J Inorg Chem. 2019, 2019(16), 2236—2244. Doi: 10.1002/ejic.201900175 (IF: 2,507).
Fonari, M.S.; Pluzhnik-Gladyr, S.M.; Kamalov, G.L.; Kravtsov, V.Kh. Cocrystallization of chiral N7,N16-bis(S-1-phenylethyl)-1,4,10,13-tetraoxo-7,16-diazacyclooctadecane-7,16-dicarboxamide with hydrochlorides of methyl ethers of leucine and valine enantiomers. J Struct Chem. 2019, 60(1), 143—150. Doi: 10.1134/S0022476619010207 (IF: 0,521).
Gelmboldt, V.O.; Kravtsov, V.Ch.; Fonari, M.S. Ammonium hexafluoridosilicates: Synthesis, structures, properties, applications. J Fluorine Chem. 2019, 221, 91—102. Doi: 10.1016/j.jfluchem.2019.04.005 (IF: 1,879).
Botezat, O.; van Leusen, J.; Hauser, J.; Decurtins, S., Liu, S.-X.; KoÌˆgerler, P.; Baca, S.G. A Spontaneous Condensation Sequence from a {Fe₆Dy₃} Wheel to a {Fe₇Dy₄} Globe. Cryst Growth Des. 2019, 19(4), 2097—2103. Doi: 10.1021/acs.cgd.8b01668 (IF: 3,972).
Lozovan, V.; Kravtsov, V.Ch.; Coropceanu, E.B.; Rotaru, P.; Siminel, A.V.; Fonari, M.S. Binuclear and polymeric Zn(II) and Cd(II) coordination compounds with chromophore N-((pyridin-4-yl)methylene)benzene-1,4-diamine obtained in situ: Preparation, structural and spectroscopic study. Inorg Chim Acta. 2019, 491, 42—51. Doi: 10.1016/j.ica.2019.03.034 (IF: 2,264).
Lozovan, V.; Coropceanu, E.B.; Bourosh, P.N.; Micu, A.; Fonari, M.S. Coordination Polymers of Zn and Cd Based on Two Isomeric Azine Ligands: Synthesis, Crystal Structures, and Luminescence Properties. Russ J Coord Chem. 2019, 45(1), 11—21. Doi: 10.1134/S107032841901007X (IF: 0,674).
Vitiu, A.A.; Coropceanu, E.B.; Bourosh, P.N. New Zn(II) and Cd(II) Coordination Polymers with 1,2-Benzenedicarboxylic Acid: Synthesis and Structures. Russ J Coord Chem. 2019, 45(2), 81—91. Doi: 10.1134/S1070328419020106 (IF: 0,674).
Coropceanu, E.; Rudic, V.; Cepoi, L.; Rudi, L.; Lozan, V.; Chiriac, T.; Miscu, V.; Bulhac, I.; Kravtsov, V.; Bourosh, P. Synthesis and Crystal Structure of [Co(DmgH)₂(Thio)₂]₂F[PF₆]. The Effect of Fluorine-Containing Co(III) Dioximates on the Physiological Processes of the Microalga Porphyridium cruentum. Russ J Coord Chem. 2019, 45(3), 200—207. Doi: 10.1134/S1070328419030059 (IF: 0,674).
Cariati, E.; Forni, A., Lucenti, E., Marinotto, D.; Previtali, A.; Righetto, S., Botta, C., Bold, V.; Kravtsov, V.; Fonari, M.S. Extrinsic Heavy Metal Atom Effect on the Solid-State Room Temperature Phosphorescence of Cyclic Triimidazole. Chem-Asian J. 2019, 14(6), 853—858. Doi: 10.1002/asia.201801604 (IF: 3,692).
Lucenti, E.; Cariati, E.; Previtali, A.; Marinotto, D.; Forni, A.; Bold, V., Kravtsov, V.; Fonari, M.; Galli, S.; Carlucci, L. Versatility of Cyclic Triimidazole to Assemble 1D, 2D, and 3D Cu(I) Halide Coordination Networks. Cryst Growth Des. 2019, 19(3), 1567—1575. Doi: 10.1021/acs.cgd.8b01199 (IF: 3,972).

Brevete de invenție/Patents

Lazarescu, A.; Melnic, E.; Bouroș, P.; Zariciuc, E. Compus hidrazonic al acidului 4-formil-3-hidroxi-2-naftoic care manifestă activitate antimicrobiană. Brevet de Invenție nr. MD 4600 C1 2019.06.30.
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Vitiu, A.; Croitor, L.; Siminel, A.; Coropceanu, E.; Bouroș, P. Compus coordinativ polimeric al cadmiului (II) cu acidul 2-hidroxi-5-[[4-[(2-piridinilamino)sulfonil]fenil]azo]benzoic și 1,2-bis(4-piridin)etan care manifestă activitate luminescentă. Brevet de Invenție nr. MD 4597 C1 2019.06.30.
Lazarescu, A.; Melnic, E.; Bouroș, P.; Zariciuc, E. Compuși coordinativi ai cuprului(II) cu S-metil-β-N-(2-hidroxi-3-carboxinaftilmetilen)ditiocarbazat care manifestă activitate antimicrobiană. Brevet de invenție MD 4611 C1 2019.07.31.
Vitiu, A.; Chișca, D.; Gorincioi, E.; Coropceanu, E.; Bouroș, P. Compus coordinativ polimeric al zincului cu ligand nou obținut prin condensare, care manifestă activitate antifungică și antibacteriană. Brevet de invenție MD 4640 B1 2019.07.31.
Melnic, E.; Kravțov, V.; Baca, S. Procedeu de obținere a c ompus ului coordinativ al cuprului(II): bis(µ 2 -1-(7-cloro-6-metil-2,3-bis(piridin-2-il)-5H-ciclopenta[b] pirazin-5-il)etanonă)-dicloro-di-cupru(II) metanol solvat. Brenet de invenție MD 4653 B1 2019.10.31.
Ciloci, A.; Baca, S.; Tiurina, J.; Labliuc, S.; Dvornina, E.; Bivol, C.; Clapco, S.; Darii, M.; Kravțov, V. Mediu nutritiv pentru cultivarea tulpinii de fungi Trichoderma koningii Oudemans CNMN FD 15 - producătoare de proteaze neutre. Brevet de invenție MD 4654 B1 2019.10.31.

2018

Gorobet, A.; Crisan, M.; Petric, M.; Bourosh, P.; Croitor, L. Structural study of Ca(II) coordination compound with triethanolamine and 4-nitrobenzoic acid. Rev Roum Chim. 2018, 63(12), 1175—1179 (IF: 0,370).
Chumakov, Yu.M.; Petrenko, P.A.; Graur,V.O.; Tsapkov, V.I.; Gulea, A.P. Crystal structure of the acetic acid solvate of N-(prop-2-en-1-yl)-2-(pyrid-2-ylmethylidene)hydrazinecarboselenoamide. J Struct Chem. 2018, 59(6), 1469—1472. Doi: 10.1134/S002247661806032X (IF: 0,521).
Зеленцов, В.И.; Дацко, Т.Я.; Политова, Е.Д.; Володина, Г.Ф.; Смолянский, А.С. Адсорбент диатомит/гидроксид алюминия для удаления фтора и его свойства. Электронная обработка материалов. 2018, 54(6), 67—76. ISSN 0013-5739. Doi: 10.5281/zenodo.1968821.
Pahontu, E.; Usataia, I.; Graur, V.; Chumakov, Yu.; Petrenko, P.; Gudumac, V.; Gulea, A. Synthesis, characterization, crystal structure of novel Cu (II), Co (III), Fe (III) and Cr (III) complexes with 2â€hydroxybenzaldehydeâ€4â€allylâ€Sâ€methylisothiosemicarbazone: Antimicrobial, antioxidant and in vitro antiproliferative activity. Appl Organomet Chem. 2018, 32(12), e4544-1—e4544-19. Doi: 10.1002/aoc.4544 (IF: 3,581).
Gel’mbol’dt, V.O.; Anisimov, V.Yu.; Shishkin, I.O.; Fonar’, M.S.; Kravtsov, V.Kh. Synthesis, structure, and anticaries activity of 2-amino-4,6-dihydroxypyrimidinium hexafluorosilicate. Pharm Chem J. 2018, 52(7), 606—610. Doi: 10.1007/s11094-018-1868-4 (IF: 0,679).
Yavolovskii, A.A.; Ivanov, Yu.E.; Grishchuk, L.V.; Kravtsov, V.Kh.; Fonar’, M.S.; Kamalov, G.L. Formation of N–S Bonds in Reactions of 2-[2-Oxo-1-(tosyloxyimino)-2-phenylethyl]pyrimidin-4(3H)-one and Its 6-derivatives with Thiourea and Potassium Thiocyanate. Russ J Org Chem. 2018, 54(8), 1213—1217. Doi: 10.1134/S1070428018080158 (IF: 0,655).
Getmanenko, Yu.A.; Allen, T.G.; Kim, H.; Hales, J.M.; Sandhu, B.; Fonari, M.S.; Suponitsky, K.Yu.; Zhang, Y.; Khrustalev, V.N.; Matichak, J.D.; Timofeeva, T.V.; Barlow, S.; Chi, S.-H.; Perry, J.W.; Marder. Linear and Third-Order Nonlinear Optical Properties of Chalcogenopyrylium-Terminated Heptamethine Dyes with Rigid, Bulky Substituents Adv Funct Mater. 2018, 28(40), 1804073-1—1804073-12. Doi: 10.1002/adfm.201804073 (IF: 13,325).
Crisan, M.; Vlase, G.; Plesu, N.; Petric, M.; Croitor, L.; Kravtsov, V.; Chumakov, Yu.; Bourosh, P. ; Vlase, T. Ethylethanolammonium 4-nitrobenzoate: Synthesis, structural characterization, thermal analysis, non-isothermal kinetic investigations and corrosion inhibitor efficiency. J Therm Anal Calorim. 2018, 134(1), 343—352. Doi: 10.1007/s10973-018-7296-6 (IF: 1,953).
Bourosh, P.; Bulhac, I.; Covaci, O.; Zubareva, V.; Mitina, T. Iron(II) Bis-α-Benzyldioximate Complexes with 3- and 4-Pyridine Hemiacetals as Axial Ligands: Synthesis, Structure, and Physicochemical Properties. Russ J Coord Chem. 2018, 44(8), 507—517. Doi: 10.1134/S1070328418080018 (IF: 0,541).
Vitiu, A.; Croitor, L.; Siminel, A.; Coropceanu, E.; Bourosh, P. A novel 2D zinc(II) coordination polymer based on 2,2'-bipyridine-4,4'-dicarboxylic acid: synthesis, crystal structure and photoluminescence property Chem J Mold. 2018, 13(1), 30—35. Doi: 10.19261/cjm.2017.479.
Cuba, L.; Bourosh, P.; Kravtsov, V.; Gorincioi, E.; Dragancea, D. Oxido-and dioxidovanadium(v) complexes with o-vanillin semicarbazone: synthesis and crystal structure. Chem J Mold. 2018, 13(1), 36—45. Doi: 10.19261/cjm.2018.477.
Gorinchoy, V.; Zubareva, V.; Melnic, E.; Kravtsov, V. Heterotrinuclear [Fe₂^IIINi^II]-µ-oxo-cluster based on salicylic acid. Synthesis, structure and physico-chemical properties. Chem J Mold. 2018, 13(1), 46—53. Doi: 10.19261/cjm.2018.483.
Voda, I.; Makhloufi, G.; Druta,V.; Lozan,V.; Shova, S.; Bourosh, P.; Kravtsov,V.; Janiak,Ch. Mixed-ligand coordination compounds based on the rigid 4,4′-bis(1-imidazolyl)biphenyl and pyridinedicarboxylate ligands. Inorg Chim Acta. 2018, 482, 526—534. Doi: 10.1016/j.ica.2018.06.038 (IF: 2,002).
Melnic, E.; Kravtsov, V.Ch.; Krämer, K.; Van Leusen, J.; Decurtins, S.; Liu, S.-X.; Kögerler, P.; Baca, S.G. Versatility of copper(II) coordination compounds with 2,3-bis(2-pyridyl) pyrazine mediated by temperature, solvents and anions choice. Solid State Sci. 2018, 82, 1—12. Doi: 10.1016/j.solidstatesciences.2018.05.008 (IF: 1,811).
Botezat, O.; Van Leusen, J.; KoÌˆgerler, P.; Baca, S.G. Tuning the Condensation Degree of {Fe^III_n} Oxo Clusters via Ligand Metathesis, Temperature, and Solvents. Inorg Chem. 2018, 57(13), 7904—7913. Doi: 10.1021/acs.inorgchem.8b00994 (IF: 4,857).
Pulya,A.V.; Seifullina, I.I.; Skorokhod, L.S.; Pavlovskii, V.I.; Kravtsov, V.Kh.; Bogza, S.L.; Suikov, S.Yu. Molecular and Crystal Structure of the Condensation Product of 2-(7-Bromo-2-Oxo-5-Phenyl-3H-1,4-Benzdiazepin-1-Yl)Acetohydrazide (Gidazepam) with Salicylic Aldehyde. J Struct Chem. 2018, 59(2), 497—501. Doi: 10.1134/S002247661802035X (IF: 0,472).
Aricu, A.N.; Kuchkova, K.I.; Secara, E.S.; Barba, A.N.; Dragalin, I.P.; Ungur, N.D.; Mel′nik, E.; Kravtsov, V.Kh. Synthesis and Structure of Drimane Sesquiterpenoids Containing Pyrimidine, Pyrazine, 1,2,4-triazole, and Carbazole Rings. Chem Nat Compd. 2018, 54(3), 455—460. Doi: 10.1007/s10600-018-2378-z (IF: 0,46).
Gorobet, A.; Vitiu, A.; Petuhov, O.; Croitor, L. Sulfur extrusion and sulfur oxidation of 2,2'-dithiodibenzoic acid in combination with Cu(II) ion and in the absence of co-ligands: Structural, spectroscopic and thermogravimetric evidence. Polyhedron. 2018, 151, 51—57. Doi: 10.1016/j.poly.2018.05.013 (IF: 1,926).
Qu, T.; Wei, Q.; Ordonez, C.; Lindline, J., Petronis, M.; Fonari, M.S.; Timofeeva, T. Tuning of Luminescent and Magnetic Properties via Metal Doping of Zn-BTC Systems. Crystals. 2018, 8(4), 162-1—162-19. Doi: 10.3390/cryst8040162 (IF: 1,566).
Kravtsov, V.Ch.; Malaestean, I.; Stingach, E.P.; Duca, Gh.G.; Macaev, F.Z.; Van Leusen, J.; Kogerler, P.; Hauser, J.; Kramer, K.; Decurtins, S.; Liu, Sh.-X.; Ghosh, A.C.; Garcia, Y.; Baca, S.G. Hexanuclear Fe(III) wheels functionalized by amino-acetonitrile derivatives. Solid State Sci. 2018, 78, 156—162. Doi: 10.1016/j.solidstatesciences.2018.02.015 (IF: 1,811).
Darii, M.; Filippova, I.G.; Hauser, J.; Decurtins, S.; Liu, S.-X.; Kravtsov, V.Ch.; Baca, S.G. Incorporation of Hexanuclear Mn(II,III) Carboxylate Clusters with a {Mn₆O₂} Core in Polymeric Structures. Crystals. 2018, 8(2), 100-1—100-11. Doi: 10.3390/cryst8020100 (IF: 1,566).
Baca, S.G. The Design of Coordination Networks from Polynuclear Mn(II, III) and Fe(III) Oxo-Carboxylate Clusters . În: Advances in Chemistry Research. Volume 43. Ed. James C. Taylor, New York, USA: Nova Science Publishers, 2018, p. 81 - 130. ISBN 978-1-53613-078-2.
Chisca, D.; Croitor, L.; Petuhov, O.; Kulikova, O.V.; Volodina, G.F.; Coropceanu, E.B.; Masunov, A.E.; Fonari, M.S. Tuning structures and emissive properties in a series of Zn(II) and Cd(II) coordination polymerscontaining dicarboxylic acids and nicotinamidepillars. Crystengcomm. 2018, 20(4), 432—447. Doi 10.1039/c7ce01988b (IF: 3,474).
Agafii, V.; Mihailov, V.; Kazak, N.; Volodina, G.; Cracan, C. Increase of wear resistance of Cr₁₈Ni₁₀Ti stainless steel by method of electric-spark alloying with electrodes of refractory metals and graphite. În: BALTTRIB 2017, Proceedings, Kaunas, 2018. 9th International Scientific Conference "BALTTRIB 2017", 16-17 November 2017, Aleksandras Stulginskis University, Kaunas district, Lithuania, p. 53—56. ISBN: 978-609-449-127-6. Doi: 10.15544/balttrib.2017.11.
Gelmboldt, V.O.; Anisimov, V.Yu.; Shyshkin, I.O.; Fonari, M.S.; Kravtsov, V.Ch. Synthesis, crystal structures, properties and caries prevention efficiency of 2-, 3-, 4-carboxymethylpyridinium hexafluorosilicates. J Fluorine Chem. 2018, 205, 15—21. Doi: 10.1016/j.jfluchem.2017.11.004 (IF: 2,101).

Brevete de invenție/Patents

Bulhac, I.; Deseatnic-Ciloci, A.; Cuba, L.; Tiurina, J., Bouroș, P.; Dragancea, D.; Clapco, S. Azotați de (2,3-butandionă-bis((izo)nicotinoilhidrazonă)-tris-aqua)fier(III) dihidrați și mediu nutritiv pentru cultivarea tulpinii de fungi miceliali usarium gibbosum CNMN FD 12. Brevet de Invenție nr. MD 4509 B1 2017.08.31.

2017

Tocana, E.; Siminel, A.; Croitor, L. Synthesis and crystal structures of luminescent mononuclear Ni(II) and Cd(II) complexes with 1,10-phenanthroline. Chemistry Journal of Moldova. 2017, 12(2), 102—108. Doi: 10.19261/cjm.2017.451.
Botezat, O. Iron-lanthanides single molecule magnet compounds. Moldavian Journal of the Physical Sciences. 2017, 16(3-4), 191—210. ISSN 1810-648X.
Crisan, M.; Halip, L.; Bourosh, P.; Chicu, S.A.; Chumakov, Yu. Synthesis, structure and toxicity evaluation of ethanolamine nitro/chloronitrobenzoates: a combined experimental and theoretical study. Chem Cent J. 2017, 11, 129-1—129-10. Doi: 10.1186/s13065-017-0346-5 (IF: 2,442).
Vitiu, A.A.; Coropceanu, E.B.; Bourosh, P.N. Synthesis and Structure of New Zn(II) and Co(II) Coordination Polymers with 1,3,5-Benzenetricarboxylic Acid. Russ J Coord Chem. 2017, 43(11), 745—752. Doi: 10.1134/S1070328417110100 (IF: 0,541).
Bourosh, P.; Bologa, O.; Deseatnic-Ciloci, A.; Tiurina, J.; Bulhac, I. Synthesis, Structure, and Biological Properties of Mixed Cobalt(III) Dioximates with Guanidine Derivatives. Russ J Coord Chem. 2017, 43(9), 591—599. Doi: 10.1134/S1070328417090019 (IF: 0,516).
Tsurkan, V.; Prodan, L.; Felea, V.; Filippova, I.; Kravtsov, V.; Günther, A.; Widmann, S.; Krug Von Nidda, H.-A.; Deisenhofer, J.; Loidl, A. Structure, magnetic susceptibility, and specific heat of the spin-orbital-liquid candidate FeSc₂S₄: Influence of Fe off-stoichiometry. Phys Rev B. 2017, 96(5), 154417. Doi: 10.1103/PhysRevB.96.054417 (IF: 3,718).
Coropceanu, E.; Croitor, L.; Ciloci, A.; Clapco, S.; Labliuc, S.; Codreanu, S.; Fonari, M. Synthesis and Structure of Some Zinc and Cadmium 1,2-Cyclohexanedione Dioximines. Russ J Coord Chem. 2017, 43(7), 433—440. Doi: 10.1134/S1070328417070053 (IF: 0,516).
Bejagam, Sh.N.; Fonari, M.S.; Averkiev, B.B.; Khrustalev, V.N.; Lindline, J.; Timofeeva, T.V. Adducts of N-Heterocyclic Drugs, Niacin, Allopurinol, and Amiloride, with 2,4-Pyridinedicarboxylic Acid Coformer. Cryst Growth Des. 2017, 17(8), 4237—4245. Doi: 10.1021/acs.cgd.7b00542 (IF: 4,425).
Vitiu, A.A.; Coropceanu, E.B.; Bourosh, P.N. Crystal structure of Co(III) α-dimethylglyoximates with imidazole. J Struct Chem. 2017, 58(3), 526—531. Doi: 10.1134/S0022476617030131 (IF: 0,536).
Coropceanu, E.B.; Croitor, L.; Ciloci, A.A.; Tyurina, ZH.P.; Dvornina, E.G.; Codreanu, C.Z.; Fonari, M.S. Synthesis and Structure of Mononuclear Zinc Complexes with Pyridine-2-Aldoxime. Russ J Coord Chem. 2017, 43(5), 278—285. Doi: 10.1134/S1070328417050025 (IF: 0,516).
Amarasekara, A.; Ha, U.; Fonari, M.S.; Bejagam, S.N.; Margeti, D. Sulfuric acid and Amberlyst-H+ catalyzed condensation reactions of renewable keto acids with paraformaldehyde: synthesis of a new dispiro bis-lactone ring system 2,9,13-trioxadispiro[4.1.4.3] tetradecane-3,6,10-trione. RSC Adv. 2017, 7(39), 23917—23923. Doi: 10.1039/c7ra02303k (IF: 3,289).
Malaestean, I.L.; Kravtsov, V.Ch.; Lipkowski, J.; Cariati, E.; Righetto, S.; Marinotto, D.; Forni, A., Fonari, M.S. Partial in Situ Reduction of Copper(II) Resulting in One-Pot Formation of 2D Neutral and 3D Cationic Copper(I) Iodide−Pyrazine Coordination Polymers: Structure and Emissive Properties. Inorg Chem. 2017, 56(9), 5141—5151. Doi: 10.1021/acs.inorgchem.7b00290 (IF: 4,82).
Croitor, L.; Coropceanu, E.; Duca, G.; Siminel, A.V.; Fonari, M.S. Nine Mn(II), Zn(II) and Cd(II) mixed-ligand coordination networks with rigid dicarboxylate and pyridine-n-aldoxime ligands: impact of the second ligand in the structures’ dimensionality and solvent capacity. Polyhedron. 2017, 129, 9—21. Doi: 10.1016/j.poly.2017.03.026 (IF: 2,108).
Plesco, I.; Postolache, V.; Volodina, G.; Zalamai, V.; Ghimpu, L.; Tiginyanu, I. Synthesis and characterization of photosensible CH₃NH₃PbI₃ and CH₃NH₃PbI_3–xCl_x perovskite crystalline films. Surf Eng Appl Elect. 2017, 53(1), 15—19. Doi: 10.3103/S1068375517010100.
Pahonțu, E.; Julea, F.; Chumakov, Y.; Petrenco, P.; Roșu, T.; Gulea, A. Synthesis, characterization, crystal structure and antiproliferative activity studies of Cu(II), Ni(II) and Co(II) complexes with 4-benzoyl-5-pyrazolones derived compounds. J Organomet Chem. 2017, 836-837, 44—55. Doi: 10.1016/j.jorganchem.2017.01.018 (IF: 2,336).
Coropceanu, E.B.; Bulhac, I.; Shtefyrtse, A.A.; Botnar, V.F.; Melenchuk, M.; Kuligin, E.; Bourosh, P.N. Synthesis, Crystal Structure, and Biological Properties of the Complex [Co(DmgH)₂(Seu)_1.4(Se-Seu)_0.5(Se2)_0.1][BF₄]. Russ J Coord Chem. 2017, 43(3), 164—171. Doi: 10.1134/S1070328417030046 (IF: 0,516).
Radu, I.; Kravtsov, V.Ch.; Ostrovsky, S.M.; Reu, O.S.; Krämer, K.; Decurtins, S.; Liu, S.-X.; Klokishner, S.I.; Baca, S.G. Tetranuclear {Co^II₂Co^III₂}, Octanuclear {Co^II₄Co^III₄}, and Hexanuclear {Co^III₃Dy^III₃} Pivalate Clusters: Synthesis, Magnetic Characterization, and Theoretical Modeling. Inorg Chem. 2017, 56(5), 2662—2676. Doi: 10.1021/acs.inorgchem.6b02827 (IF: 4,82).
Botezat, O.; Van Leusen, J.; Kravtsov, V.Ch.; KoÌˆgerler, P.; Baca, S.G. Ultralarge 3d/4f Coordination Wheels: From Carboxylate/Amino Alcohol-Supported {Fe4Ln2} to {Fe18Ln6}. Inorg Chem. 2017, 56(4), 1814—1822. Doi: 10.1021/acs.inorgchem.6b02100 (IF: 4,82).
Croitor, L.; Chisca, D.; Coropceanu, E.; Volodina, G.; Petuhov, O.; Fonari, M. Solvent-rich layered cobalt(II) 1,4-benzenedicarboxylate based on binuclear {Co₂(μ-OH₂)(RCOO)₂} secondary building unit. J Mol Struct. 2017, 1137, 136—141. Doi: 10.1016/j.molstruc.2017.02.018 (IF: 1,78).
Bulhac, I.; Danilescu, O.; Rija, A.; Shova, S.; Kravtsov, V.Ch.; Bourosh, P. Cobalt(II) Complexes with Pentadentate Schiff Bases 2,6-Diacetylpyridine Hydrazones: Syntheses and Structures. Russ J Coord Chem. 2017, 43(1), 21—36. Doi: 10.1134/S1070328417010018 (IF: 0,5

Laboratory of Physical Methods of Solid
State Investigation ″Tadeusz Malinowski ″

Head of laboratory:

Laboratory of Physical Methods of Solid State Investigation ″Tadeusz Malinowski ″

Head of laboratory:

Laboratory of Physical Methods of Solid
State Investigation ″Tadeusz Malinowski ″